Latex paint covalent crosslink additive


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Cross-link

The inventive paint or open-time extender comprises mostly water. Table 2 shows that when the inventive paint extender of Example 1 is added to a low VOC latex-based paint, the paint's open time is improved over the paint with a conventional paint extender added and over the paint with water added. Under one approach, open time can be extended by adding volatile organic compounds VOC such as glycols into the emulsion paint formulation. Nature Methods. A 3 mil drawdown is prepared on a substrate and dried. Where chemical cross-links are covalent bonds, physical cross-links are formed by weak interactions. Two samples of the dried paint film are pressed together at room temperature and at elevated temperature.
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USB2 - Latex based open-time extenders for low VOC paints - Google Patents

The second phase of the multi-stage sequential emulsion polymerization is the formation of the relatively hard core by feeding a monomer mixture that forms polymers with relatively higher T g values e. The latex particles in the open-time extender are preferably sequentially designed polymers. The resulting modification of mechanical properties depends strongly on the cross-link density. In most cases, cross-linking is irreversible, and the resulting thermosetting material will degrade or burn if heated, without melting. It will be apparent to persons skilled in the relevant art that various changes in form and detail can be made therein without departing from the spirit and scope of the invention.
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US8034871B2 - Latex based open-time extenders for low VOC paints - Google Patents

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Description: For the syneresis test, the paint extender is added to the paint, mixed and allowed to stand. Cross-linking can also be induced in materials that are normally thermoplastic through exposure to a radiation source, such as electron beam exposure, [5] gamma radiation , or UV light. Subunit structure is deduced, since crosslinkers bind only surface residues in relatively close proximity in the native state. The color rub-up test generally tests a color change in a wet film, caused by rubbing with the finger, which may not disappear.

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